Ray of Light for CRT Recycling

Cathode Ray Tubes may have disappeared from our shops, but the number entering the waste stream is yet to peak in Europe, while demand for the leaded glass they contain has evaporated. Ben Messenger looks at an award winning technology developed by a small firm in Manchester, England that combines heat and chemistry to extract lead and clean glass. It may only be 15 years since the world was wowed by the introduction of the first plasma screen television - a 42 inch Fujitsu model available in Sears for a mere $14,999 - but consumer electronics have since moved on apace, and manufacture of the Cathode Ray Tubes (CRTs) which once dominated the TV market has all but ended. For the waste and recycling industry, which has traditionally sold the glass from end-of-life television sets back to the CRT manufacturers, the rise of the flat screen has created something of a conundrum - what to do with the leaded glass? Huge numbers of obsolete television sets and computer monitors have been entering the waste stream, a figure which has been estimated to peak in Europe in 2013. Across the world, electronics recycling programmes are collecting growing quantities of CRTs, while at the same time the end uses for recycled CRT glass, which generally constitutes between 15 kg and 30 kg per set, are disappearing. The temperature inside the main unit is in excess of 1000°C to extract the toxic lead from the glass while creating no emissions According to the Partnership for Action on Computing Equipment (PACE) - a multi-stakeholder partnership that provides a forum for governments, industry and NGOs to tackle end-of-life computing equipment - although CRTs are still being manufactured, and clean leaded glass can be used in this manufacture, the market will continue to decline. Additionally, there is often insufficient value in CRT glass to economically support its shipment to facilities which are mostly located in Asia, where it can be used to make new CRT glass or other leaded-glass applications. As a result it is often discarded or dumped in places where lead may leach into soil and groundwater. "Our industry is at an interesting crossroads when it comes to CRT glass," explains Robert Erie, CEO of E-World Online, which runs a nationwide network of collectors and recyclers in the U.S. to help consumer electronics manufacturers comply with the extended producer responsibility guidelines being enacted in many states. "In my 12 years in the electronics recycling field, this is the first time that I've seen an e-waste material stream become obsolete and markets dry up so quickly." In recognition of the problem, the most recent update to the Sanctioned Interpretations of the e-Stewards Standard - a third party certification programme for electronics recyclers run by the Basal Action Network (BAN) - makes allowances for its members to store CRT glass beyond 12 months, until acceptable destinations are available - providing certain criteria are met. The challenge According to the U.S. Consumer Electronics Association (CEA) many U.S. recyclers have growing stockpiles of CRT glass, and to date no truly feasible market for it has emerged. In the U.S. alone several hundred million kilos of CRT glass will be collected for recycling in 2012. In California this issue has resulted in a proposal to allow landfilling of the units. In a bid to find solutions to the problem, late last year the CEA laid down an Eco-Challenge to develop compelling economic and environmentally preferable solutions for recycling CRTs. This was in partnership with the Environmental Defense Fund (EDF), a non-profit environmental organisation and InnoCentive, a specialist in 'crowdsourcing' and open innovation. One of the entrants for the challenge, and one of the eventual winners, was Manchester, UK based Nulife Glass, which has developed a solution to separate the lead from leaded CRT glass using a highly efficient electric furnace and a combination of chemicals to produce both clean glass and lead. According to the company, the process has no emissions, creates no waste and avoids the export of hazardous material around the globe. Speaking to Waste Management World, Simon Greer, director of Nulife Glass and inventor of the process explains that the "Eureka" moment came in 2001, when, using a combination of heat and chemistry, he managed to squeeze a tiny amount of lead out of glass using a furnace and realised what the chemical formula was to do it. He then set about refining the process through trial and error with the construction of a number of small furnaces. "I predicted for the past five or six years that the day will come when there will be no recycling of glass back into TVs. It was not a fantastic revelation. It was blatantly obvious that that would be the case. The price of panel TVs would fall and on that basis the CRT would end. So we've carried on doing what we're doing with the confidence of knowing that day would come. And it has come crashing all at the same time. There are increasing numbers of TVs coming into the waste stream, and diminishing outlets," explains Greer. The process The first stage in Nulife's process is to separate the panel glass from the leaded glass, which is crushed and treated with chemicals to assist the lead extraction. The process utilises a specially designed electrolytic converter where the CRT glass and process chemicals are melted under strictly controlled conditions to free metallic lead from the glass, which is tapped off to form lead ingots. The process is continuous and has the capacity to handle 10 tonnes per day - equivalent to around 60 tonnes of end-of-life CRT televisions. To increase energy efficiency, the process utilises super-efficient insulation so that while the temperature inside the main melting unit is in excess of 1000°C, the outside never exceeds 60°C. In addition to being energy efficient, the converter has negligible emissions, meaning that there is no requirement for expensive extraction and filtration systems. The lead purity achieved by the process is typically better than 99.7% According to Greer the process uses around $0.50 worth of electricity for each TV treated and recovers around $2 worth of lead, as well as clean glass. The glass, which has End of Waste approval from the Environment Agency in the UK, is of relatively low value and is being used by construction materials company, Tarmac, which is adding a small percentage to concrete blocks. The lead is sold to lead dealers at a price based on London Metal Exchange (LME) prices. The company built its first furnace at its own premises, and is currently in the process of building another for electronics recycler, SWEEEP Kuusakoski at its site in Kent, UK. The recycling company is collaborating with Nulife Glass and its partner company, Kuusakoski Oy of Finland in refining the system's features and tailoring the furnace to its exact needs. SWEEEP has also developed new crushing and separation equipment to be ready in time for the new furnace. International demand On the subject of demand Greer is upbeat: "Everyday from somewhere around the world we get contacted by people asking us about our technology," he says. "We've had visitors from Japan, Korea, Taiwan, many from the U.S., from absolutely everywhere. I would think there are probably 10 organisations that are in the process of enquiring about permits to operate their own furnaces." But the company's also thinking beyond simply marketing its invention, and is planning on using its technology at its own CRT glass recycling facilities, as well as extending its existing site in Manchester. Furthermore, according to Greer the wheels are in motion on the development of sites in New York State, as well as two other target areas in the U.S. Both the expansion of the UK site and the development of the proposed New York facility are well underway, with the company currently in dialogue with power companies and with the permitting authorities for the State. For other locations, such as Japan, the company is still in negotiations with prospective partners. With the price of lead in excess of $2000 per tonne, capturing the huge quantities availble in end-of-life CRTs could be alchemy for the 21st century According to Greer demand from the U.S. is strong, with the company receiving daily phone calls from potential customers looking to offload CRT glass, and even making enquiries into the cost of shipping the glass to Nulife's Manchester facility. The company plans to maximise this potential customer base by offering a "menu" of services at it facilities, accepting whole screens, mixed glass or just the leaded glass. Conclusion While flat screen technology has clearly superseded CRTs in just about every application, from the smallest ATM screens to the biggest of TVs, for many years to come there will be huge quantities of redundant displays entering the waste stream. In the U.S. alone hundreds of millions of kilos of CRTs will be collected in 2012. Globally it is estimated that at least 1.9 billon screens are still in use. The correct disposal of these will provide an ongoing problem and the recycling industry is scrambling for environmentally acceptable solutions. For centuries the objectives of Alchemy have varied, from discovering the elixir of life to turning lead into gold or silver. With the traditional closed loop, CRT glass to CRT glass recycling options having all but disappeared, and a growing need to preserve precious resources, the development of a technology to recover both lead and glass from an abundant and potentially hazardous waste stream could be just the kind of 'alchemy' the 21st century needs. Ben Messenger is the associate editor of Waste Management World magazine.Email: benm@pennwell.com More Waste Management World Articles Waste Management World Issue Archives Free Magazine Subscription Free Email Newsletter